MARC details
| 000 -LEADER |
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| fixed length control field |
10793nam a22002657a 4500 |
| 003 - CONTROL NUMBER IDENTIFIER |
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| control field |
TH-BaNU |
| 005 - DATE AND TIME OF LATEST TRANSACTION |
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| control field |
20220208140809.0 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
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| fixed length control field |
220208b2017 ||||| |||| 00| 0 eng d |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
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| International Standard Book Number |
978-1-118-76723-8 |
| 040 ## - CATALOGING SOURCE |
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| Original cataloging agency |
TH-BaNU |
| 050 ## - LIBRARY OF CONGRESS CALL NUMBER |
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| Classification number |
TD196.O73 S411e |
| Item number |
2017 |
| 100 ## - MAIN ENTRY--PERSONAL NAME |
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| Personal name |
René P Schwarzenbach |
| 245 ## - TITLE STATEMENT |
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| Title |
Environmental Organic Chemistry |
| 250 ## - EDITION STATEMENT |
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| Edition statement |
3rd Edition |
| 260 ## - PUBLICATION, DISTRIBUTION, ETC. |
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| Place of publication, distribution, etc. |
Somerset |
| Name of publisher, distributor, etc. |
John Wiley & Sons |
| Date of publication, distribution, etc. |
2017 |
| 505 ## - FORMATTED CONTENTS NOTE |
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| Formatted contents note |
1 General Topic and Overview 1<br/><br/>1.1 Introduction 2<br/><br/>1.2 Assessing Organic Chemicals in the Environment 4<br/><br/>1.3 What is This Book All About? 7<br/><br/>1.4 Bibliography 14<br/><br/>Part I Background Knowledge 17<br/><br/>2 Background Knowledge on Organic Chemicals 19<br/><br/>2.1 The Makeup of Organic Compounds 20<br/><br/>2.2 Intermolecular Forces Between Uncharged Molecules 37<br/><br/>2.3 Questions and Problems 40<br/><br/>2.4 Bibliography 43<br/><br/>3 The Amazing World of Anthropogenic Organic Chemicals 45<br/><br/>3.1 Introduction 47<br/><br/>3.2 A Lasting Global Problem: Persistent Organic Pollutants (POPs) 47<br/><br/>3.3 Natural but Nevertheless Problematic: Petroleum Hydrocarbons 48<br/><br/>3.4 Notorious Air and Groundwater Pollutants: Organic Solvents 53<br/><br/>3.5 Safety First: Flame Retardants All Around Us 56<br/><br/>3.6 How to Make Materials “Repellent”: Polyfluorinated Chemicals (PFCs) 58<br/><br/>3.7 From Washing Machines to Surface Waters: Complexing Agents, Surfactants, Whitening Agents, and Corrosion Inhibitors 60<br/><br/>3.8 Health, Well-Being, and Water Pollution: Pharmaceuticals and Personal Care Products 63<br/><br/>3.9 Fighting Pests: Herbicides, Insecticides, and Fungicides 65<br/><br/>3.10 Our Companion Compounds: Representative Model Chemicals 69<br/><br/>3.11 Questions 72<br/><br/>3.12 Bibliography 73<br/><br/>4 Background Thermodynamics, Equilibrium Partitioning and Acidity Constants 81<br/><br/>4.1 Important Thermodynamic Functions 83<br/><br/>4.2 Using Thermodynamic Functions to Quantify Equilibrium Partitioning 89<br/><br/>4.3 Organic Acids and Bases I: Acidity Constant and Speciation in Natural Waters 98<br/><br/>4.4 Organic Acids and Bases II: Chemical Structure and Acidity Constant 107<br/><br/>4.5 Questions and Problems 116<br/><br/>4.6 Bibliography 119<br/><br/>5 Earth Systems and ComPartments 121<br/><br/>5.1 Introduction 123<br/><br/>5.2 The Atmosphere 125<br/><br/>5.3 Surface Waters and Sediments 131<br/><br/>5.4 Soil and Groundwater 148<br/><br/>5.5 Biota 154<br/><br/>5.6 Questions 155<br/><br/>5.7 Bibliography 158<br/><br/>6 Environmental Systems: Physical Processes and Mathematical Modeling 165<br/><br/>6.1 Systems and Models 167<br/><br/>6.2 Box Models: A Concept for a Simple World 174<br/><br/>6.3 When Space Matters: Transport Processes 191<br/><br/>6.4 Models in Space and Time 196<br/><br/>6.5 Questions and Problems 203<br/><br/>6.6 Bibliography 211<br/><br/>Part II Equilibrium Partitioning in Well-Defined Systems 213<br/><br/>7 Partitioning Between Bulk Phases: General Aspects and Modeling Approaches 215<br/><br/>7.1 Introduction 216<br/><br/>7.2 Molecular Interactions Governing Bulk Phase Partitioning of Organic Chemicals 217<br/><br/>7.3 Quantitative Approaches to Estimate Bulk Phase Partition Constants/Coefficients: Linear Free Energy Relationships (LFERs) 225<br/><br/>7.4 Questions 232<br/><br/>7.5 Bibliography 234<br/><br/>8 Vapor Pressure (pi∗) 237<br/><br/>8.1 Introduction and Theoretical Background 238<br/><br/>8.2 Molecular Interactions Governing Vapor Pressure and Vapor Pressure Estimation Methods 246<br/><br/>8.3 Questions and Problems 253<br/><br/>8.4 Bibliography 257<br/><br/>9 Solubility (Csatiw ) and Activity Coefficient (?satiw ) in Water; Air–Water Partition Constant (Kiaw) 259<br/><br/>9.1 Introduction and Thermodynamic Considerations 261<br/><br/>9.2 Molecular Interactions Governing the Aqueous Activity Coefficient and the Air–Water Partition Constant 267<br/><br/>9.3 LFERs for Estimating Air–Water Partition Constants and Aqueous Activity Coefficients/Aqueous Solubilities 270<br/><br/>9.4 Effect of Temperature, Dissolved Salts, and pH on the Aqueous Activity Coefficient/Aqueous Solubility and on the Air–Water Partition Constant 272<br/><br/>9.5 Questions and Problems 282<br/><br/>9.6 Bibliography 285<br/><br/>10 Organic Liquid–Air and Organic Liquid–Water Partitioning 289<br/><br/>10.1 Introduction 291<br/><br/>10.2 Thermodynamic Considerations and Comparisons of Different Organic Solvents 291<br/><br/>10.3 The Octanol–Water System: The Atom/Fragment Contribution Method for Estimation of the Octanol–Water Partition<br/><br/>Constant 298<br/><br/>10.4 Partitioning Involving Organic Solvent–Water Mixtures 301<br/><br/>10.5 Evaporation and Dissolution of Organic Compounds from Organic Liquid Mixtures–Equilibrium<br/><br/>Considerations 307<br/><br/>10.6 Questions and Problems 311<br/><br/>10.7 Bibliography 317<br/><br/>11 Partitioning of Nonionic Organic Compounds Between Well-Defined Surfaces and Air or Water 321<br/><br/>11.1 Introduction 322<br/><br/>11.2 Adsorption from Air to Well-Defined Surfaces 322<br/><br/>11.3 Adsorption from Water to Inorganic Surfaces 335<br/><br/>11.4 Questions and Problems 342<br/><br/>11.5 Bibliography 345<br/><br/>Part III Equilibrium Partitioning in Environmental Systems 349<br/><br/>12 General Introduction to Sorption Processes 351<br/><br/>12.1 Introduction 352<br/><br/>12.2 Sorption Isotherms and the Solid–Water Equilibrium Distribution Coefficient (Kid) 354<br/><br/>12.3 Speciation (Sorbed versus Dissolved or Gaseous), Retardation, and Sedimentation 360<br/><br/>12.4 Questions and Problems 366<br/><br/>12.5 Bibliography 368<br/><br/>13 Sorption from Water to Natural Organic Matter (NOM) 369<br/><br/>13.1 The Structural Diversity of Natural Organic Matter Present in Aquatic and Terrestrial Environments 371<br/><br/>13.2 Quantifying Natural Organic Matter–Water Partitioning of Neutral Organic Compounds 376<br/><br/>13.3 Sorption of Organic Acids and Bases to Natural Organic Matter 388<br/><br/>13.4 Questions and Problems 392<br/><br/>13.5 Bibliography 397<br/><br/>14 Sorption of Ionic Organic Compounds to Charged Surfaces 405<br/><br/>14.1 Introduction 407<br/><br/>14.2 Cation and Anion Exchange Capacities of Solids in Water 408<br/><br/>14.3 Ion Exchange: Nonspecific Adsorption of Ionized Organic Chemicals from Aqueous Solutions to Charged Surfaces 414<br/><br/>14.4 Surface Complexation: Specific Bonding of Organic Compounds with Solid Phases in Water 426<br/><br/>14.5 Questions and Problems 432<br/><br/>14.6 Bibliography 436<br/><br/>15 Aerosol–Air Partitioning: Dry andWet Deposition of Organic Pollutants 441<br/><br/>15.1 Origins and Properties of Atmospheric Aerosols 442<br/><br/>15.2 Assessing Aerosol–Air Partition Coefficients (KiPMa) 445<br/><br/>15.3 Dry and Wet Deposition 453<br/><br/>15.4 Questions and Problems 459<br/><br/>15.5 Bibliography 464<br/><br/>16 Equilibrium Partitioning From Water and Air to Biota 469<br/><br/>16.1 Introduction 471<br/><br/>16.2 Predicting Biota–Water and Biota–Air Equilibrium Partitioning 471<br/><br/>16.3 Bioaccumulation and Biomagnification in Aquatic Systems 485<br/><br/>16.4 Bioaccumulation and Biomagnification in Terrestrial Systems 498<br/><br/>16.5 Baseline Toxicity (Narcosis) 503<br/><br/>16.6 Questions and Problems 507<br/><br/>16.7 Bibliography 514<br/><br/>Part IV Mass Transfer Processes in Environmental Systems 523<br/><br/>17 Random Motion, Molecular and Turbulent Diffusivity 525<br/><br/>17.1 Random Motion 526<br/><br/>17.2 Molecular Diffusion 534<br/><br/>17.3 Other Random Transport Processes in the Environment 545<br/><br/>17.4 Questions and Problems 550<br/><br/>17.5 Bibliography 557<br/><br/>18 Transport at Boundaries 559<br/><br/>18.1 The Role of Boundaries in the Environment 560<br/><br/>18.2 Bottleneck Boundaries 562<br/><br/>18.3 Wall Boundaries 567<br/><br/>18.4 Hybrid Boundaries 572<br/><br/>18.5 Questions and Problems 577<br/><br/>18.6 Bibliography 580<br/><br/>19 Air–Water Exchange 581<br/><br/>19.1 The Air–Water Interface 583<br/><br/>19.2 Air–Water Exchange Models 585<br/><br/>19.3 Measurement of Air–Water Exchange Velocities 592<br/><br/>19.4 Air–Water Exchange in Flowing Waters 599<br/><br/>19.5 Questions and Problems 604<br/><br/>19.6 Bibliography 613<br/><br/>20 Interfaces Involving Solids 617<br/><br/>20.1 The Sediment–Water Interface 618<br/><br/>20.2 Transport in Unsaturated Soil 626<br/><br/>20.3 Questions and Problems 630<br/><br/>20.4 Bibliography 634<br/><br/>Part V Transformation Processes 635<br/><br/>21 Background Knowledge on Transformation Reactions of Organic Pollutants 637<br/><br/>21.1 Identifying Reactive Sites Within Organic Molecules 638<br/><br/>21.2 Thermodynamics of Transformation Reactions 643<br/><br/>21.3 Kinetics of Transformation Reactions 650<br/><br/>21.4 Questions and Problems 657<br/><br/>21.5 Bibliography 661<br/><br/>22 Hydrolysis And ReactionsWith Other Nucleophiles 663<br/><br/>22.1 Nucleophilic Substitution and Elimination Reactions Involving Primarily Saturated Carbon Atoms 665<br/><br/>22.2 Hydrolytic Reactions of Carboxylic and Carbonic Acid Derivatives 680<br/><br/>22.3 Enzyme-Catalyzed Hydrolysis Reactions: Hydrolases 695<br/><br/>22.4 Questions and Problems 701<br/><br/>22.5 Bibliography 710<br/><br/>23 Redox Reactions 715<br/><br/>23.1 Introduction 716<br/><br/>23.2 Evaluating the Thermodynamics of Redox Reactions 719<br/><br/>23.3 Examples of Chemical Redox Reactions in Natural Systems 730<br/><br/>23.4 Examples of Enzyme-Catalyzed Redox Reactions 747<br/><br/>23.5 Questions and Problems 756<br/><br/>23.6 Bibliography 765<br/><br/>24 Direct Photolysis in Aquatic Systems 773<br/><br/>24.1 Introduction 775<br/><br/>24.2 Some Basic Principles of Photochemistry 776<br/><br/>24.3 Light Absorption by Organic Compounds in Natural Waters 788<br/><br/>24.4 Quantum Yield and Rate of Direct Photolysis 800<br/><br/>24.5 Effects of Solid Sorbents (Particles, Soil Surfaces, Ice) on Direct Photolysis 803<br/><br/>24.6 Questions and Problems 804<br/><br/>24.7 Bibliography 811<br/><br/>25 Indirect Photolysis: Reactions with Photooxidants in Natural Waters and in the Atmosphere 815<br/><br/>25.1 Introduction 816<br/><br/>25.2 Indirect Photolysis in Surface Waters 817<br/><br/>25.3 Indirect Photolysis in the Atmosphere (Troposphere): Reaction with Hydroxyl Radical (HO∙) 829<br/><br/>25.4 Questions and Problems 833<br/><br/>25.5 Bibliography 838<br/><br/>26 Biotransformations 845<br/><br/>26.1 Introduction 847<br/><br/>26.2 Some Important Concepts about Microorganisms Relevant to Biotransformations 848<br/><br/>26.3 Initial Biotransformation Strategies 858<br/><br/>26.4 Rates of Biotransformations 864<br/><br/>26.5 Questions and Problems 882<br/><br/>26.6 Bibliography 889<br/><br/>27 Assessing Transformation Processes Using Compound-Specific Isotope Analysis (CSIA) 897<br/><br/>27.1 Introduction, Methodology, and Theoretical Background 898<br/><br/>27.2 Using CSIA for Assessing Organic Compound Transformations in Laboratory and Field Systems 914<br/><br/>27.3 Questions and Problems 930<br/><br/>27.4 Bibliography 936<br/><br/>Part VI Putting Everything Together 945<br/><br/>28 Exposure Assessment of Organic Pollutants Using Simple Modeling Approaches 947<br/><br/>28.1 One-Box Model: The Universal Tool for Process Integration 948<br/><br/>28.2 Assessing Equilibrium Partitioning in Simple Multimedia Systems 952<br/><br/>28.3 Simple Dynamic Systems 956<br/><br/>28.4 Systems Driven by Advection 960<br/><br/>28.5 Bibliography 974 |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
Organic compounds Environmental aspects. |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
Water Organic compound content. |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
Organic compounds Environmental aspects Problems |
| 700 ## - ADDED ENTRY--PERSONAL NAME |
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| Personal name |
Philip M Gschwend |
| 700 ## - ADDED ENTRY--PERSONAL NAME |
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| Personal name |
Dieter M Imboden |
| 850 ## - HOLDING INSTITUTION |
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| Holding institution |
Kuakarun Nursing Library |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
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| Source of classification or shelving scheme |
Library of Congress Classification |
| Koha item type |
General Book |
| 998 ## - STAFF NAME (NMU) |
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| Cataloger |
nuch |
